コンテンツへスキップ原著論文 / Original Articles
- under preparation
S. Shoji*
- Biomimetic light-harvesting antennas via self-assembly of chemically programmed chlorophylls
S. Matsubara*, S. Shoji, H. Tamiaki
Chem. Commun., 60, 12513–12524 (2022).
DOI: 10.1039/D4CC04363D
- Structural and electrochemical properties of mononuclear copper(II) complexes with pentadentate ethylenediamine-based ligands with pyridine/quinoline/isoquinoline/quinoxaline binding sites
Y. Mikata*, M. Akedo, E. Hamamoto, S. Yoshida, S. Shoji, Y. Ohsedo, T. Storr, Y. Funahashi, T. Matsuo
Dalton Trans., 53, 16716–16732 (2024).
DOI: 10.1039/D4DT02363C
- Luminescence changeable CO2-storage cylinder: Triple-stranded helical Eu(III)/Tb(III) fluorinated MOFs with amide linkers
J. Hayashi, S. Iwamura, Y. Nakasaka, M. Wang, S. Shoji, Y. Kitagawa, K. Fushimi, S. Mukai, Y. Hasegawa*
Chem. Eur. J., 30, e202403224 (2024).
DOI: 10.1002/chem.202403224
- Composition Analysis of Corrosion Products on Steel by Machine Learning of Optical Microscopic Images
Y. Tsuji, K. Hirasawa, S. Shoji, Y. Kitagawa, Y. Hasegawa, K. Fushimi*
Tetsu-to-Hagane, in press (2024).
DOI: 10.2355/tetsutohagane.TETSU-2024-056
- Alkyl substituents control the Cd2+-selectivity of fluorescence enhancement in N,N’-bis(2-quinolylmethyl)ethylenediamine derivatives
Y. Mikata,* S. Yasuda, T. Hagiwara, H. Konno, S. Shoji
Inorg. Chim. Acta, 571, 122218 (2024).
DOI: 10.1016/j.ica.2024.122218
- Guest-responsive near-infrared luminescent metal-organic-cage organized by porphyrin dyes and Yb(III) complexes
S. Hosoya, S. Shoji*, T. Nakanishi, M. Kobayashi, M. Wang, K. Fushimi, T. Taketsugu, Y. Kitagawa, Y. Hasegawa*
Inorg. Chem., 63, 10108–10113 (2024).
DOI: 10.1021/acs.inorgchem.4c01348
- Cd2+-Specific fluorescence response of methoxy-substituted N,N-bis(2-quinolylmethyl)-2-methoxyaniline derivatives
Y. Mikata*, N. Tosaka, S. Yasuda, Y. Sakurai, S. Shoji, H. Konno, T. Matsuo
Inorg. Chem., 63, 8026–8037 (2024).
DOI: 10.1021/acs.inorgchem.3c04395
- Cd2+-Selective fluorescence enhancement of N,N’-bis(2-quinolylmethyl)-N,N’-dimethyl-1,2-phenylenediamine derivatives
Y. Mikata*, K. Kawakami, M. Nagaoka, S. Shoji, H. Konno, T. Matsuo
Inorg. Chim. Acta, 565, 121968 (2024).
DOI: 10.1016/j.ica.2024.121968
- Passive film formed on Si-Mn steel in boric acid-borate buffer at 6.5
K. Fushimi*, K. Higa, A. Fujimura, S. Shoji, Y. Kitagawa, Y. Hasegawa, H. Katayama
J. Electrochem. Soc., 171, 021502 (2024).
DOI: 10.1149/1945-7111/ad27b7
- Structure-changeable luminescent Eu(III) complex as a human cancer grade probing system for brain tumor diagnosis
M. Wang*, M. Kono, Y. Yamaguchi, J. Islam, S. Shoji, Y. Kitagawa, K. Fushimi, G. Matsuba, A. Yamamoto, M. Tanaka, M. Tsuda, S. Tanaka, Y. Hasegawa*
Sci. Rep., 14, 778 (2024).
DOI: 10.1038/s41598-023-50138-9
- Cd2+-Selective fluorescence enhancement of bisquinoline derivatives with 2-aminoethanol skeleton
Y. Mikata*, A. Tsuruta, H. Koike, S. Shoji, H. Konno
Molecules, 29, 369 (2024).
DOI: 10.3390/molecules29020369
- Quantitative evaluation of hydrogen absorption by detecting non-absorbed hydrogen in electrochemical permeation test
Y. Mizushiri, S. Shoji, Y. Kitagawa, Y. Hasegawa, K. Fushimi*
Int. J. Hydrogen Energy, 67, 1243–1247 (2024).
DOI: 10.1016/j.ijhydene.2023.10.236
- Size-control synthesis and luminescence properties of the Eu(III) coordination particles
M. Enokido, K. Sasaki, S. Shoji, M. Wang, K. Fushimi, Y. Kitagawa, Y. Hasegawa*
J. Phys. Chem. C, 127, 23785–23791 (2023).
DOI: 10.1021/acs.jpcc.3c06499
- Evaluation of oxygen-containing pentadentate ligands with pyridine/quinoline/isoquinoline binding sites via the structural and electrochemical properties of mononuclear copper(II) complexes
Y. Mikata*, M. Uchida, H. Koike, S. Shoji, Y. Ohsedo, Y. Kawai, T, Matsuo
Dalton Trans., 52, 17375–17388 (2023).
DOI: 10.1039/D3DT02814C
- Sandglass-typed single luminophore for water mapping measurements: Intra-molecular energy migration in hydrophilic Tb(III)/Sm(III) cluster
Y. Hasegawa*, Y. Konishi, M. Enokido, S. Shoji, M. Wang, K. Fushimi, Y. Kitagawa
Inorg. Chem., 62, 16794–16800 (2023).
DOI: 10.1021/acs.inorgchem.3c02219
- Investigation of the dissolution/passivation mechanisms on Fe-Cr alloys in acidic Na2SO4 solution using online ICP-OES
A. Fujimura, S. Shoji, Y. Kitagawa, Y. Hasegawa, T. Doi, K. Fushimi*
Electrochim. Acta, 463, 142843 (2023).
DOI: 10.1016/j.electacta.2023.142843
- Thermally-assisted photosensitized emission in a trivalent terbium complex
Y. Kitagawa* K. Shima, T. Nakai, M. Kumagai, S. Omagari, P. P. Ferreira da Rosa, S. Shoji, K. Fushimi, Y. Hasegawa*
Commun. Chem., 6, Article number: 122 (2023).
DOI: 10.1038/s42004-023-00922-5
- Characteristic stacked structures and luminescent properties of dinuclear lanthanide complexes with pyrene units
T. Nakai, K. Shima, S. Shoji, K. Fushimi, Y. Hasegawa*, Y. Kitagawa*
Front. Chem., 11, 1154012 (2023).
DOI: 10.3389/fchem.2023.1154012
- Initiation of Sulfide Stress Cracking Using Potentiostatic Liquid-Phase Ion Gun
K. Fushimi*, Y. Yanagimoto, S. Nakatsuji, S. Shoji, Y. Kitagawa, Y. Hasegawa, K. Baba
J. Electrochem. Soc., 170, 041508 (2023).
DOI: 10.1149/1945-7111/accd26
- Synthesis of Bicyclo[1.1.1]pentane (BCP)-Based Straight-Shaped Diphosphine Ligands
H. Takano, H. Katsuyama, H. Hayashi, M. Harukawa, M. Tsurui, S. Shoji, Y. Hasegawa, S. Maeda, T. Mita*
Angew. Chem. Int. Ed., 62, e202303435 (2023).
DOI: 10.1002/anie.202303435
- Luminescent lanthanide complexes for effective oxygen-sensing and singlet oxygen generation
Y. Kitagawa*, T. Nakai, S. Hosoya, S. Shoji, Y. Hasegawa*
ChemPlusChem, 2023, e202200445 (2023).
DOI: 10.1002/cplu.202200445
- Enhanced circularly polarized luminescence of chiral Eu(III) coordination polymers with structural strain
M. Tsurui, Y. Kitagawa, S. Shoji, K. Fushimi, Y. Hasegawa*
Dalton Trans., 52, 796–805 (2023).
DOI: 10.1039/D2DT03422K
- Plant growth acceleration using a transparent Eu3+-painted UV-to-red conversion film
S. Shoji*, H. Saito*, Y. Jitsuyama, K. Tomita, Q. Haoyang, Y. Sakurai, Y. Okazaki, K. Aikawa, Y. Konishi, K. Sasaki, K. Fushimi, Y. Kitagawa, T. Suzuki*, Y. Hasegawa*
Sci. Rep., 12, Article number: 17155 (2022).
DOI: 10.1038/s41598-022-21427-6
日刊工業新聞「植物成長促すフィルム 紫外線→赤色光変換」(2022年10月27日).
Yahoo!ニュース「野菜の重量4割増、植物の成長促す透明フィルムがスゴい」(2022年10月28日).
読売新聞「植物の成長促すビニール」(2022年11月6日).
科学新聞「フィルムに塗布して植物成長促進」(2022年11月18日).
Chem-Station 第455回スポットライトリサーチ「赤色発光する希土類錯体で植物成長促進の実証に成功」(2022年12月30日).
- Amorphous lanthanide complexes for organic luminescent materials
J. Hayashi, S. Shoji, Y. Kitagawa, Y. Hasegawa*
Coord. Chem. Rev., 467, 214607 (2022).
DOI: 10.1016/j.ccr.2022.214607
- Development of a quasi-on-time ICP-OES for analyzing electrode reaction products
A. Fujimura, S. Shoji, Y. Kitagawa, Y. Hasegawa, T. Doi, K. Fushimi*
Electrochim. Acta, 433, 141246 (2022).
DOI: 10.1016/j.electacta.2022.141246
- Effective photosensitization in excited-state equilibrium: Brilliant luminescence of TbIII coordination polymers through ancillary ligand modifications
Y. Kitagawa*, R. Moriake, T. Akama, K. Saito, K. Aikawa, S. Shoji, K. Fushimi, M. Kobayashi, T. Taketsugu, Y. Hasegawa*
ChemPlusChem, 87, e202200151 (2022).
DOI: 10.1002/cplu.202200151
- Self-assembly of a zinc bacteriochlorophyll-d analog with a lipophilic amide group in the 17-substituent
S. Shoji*, V. Stepanenko, F. Würthner*, H. Tamiaki*
Bull. Chem. Soc. Jpn., 95, 1083–1085 (2022).
DOI: 10.1246/bcsj.20220128
- Preparation of photonic molecular trains via soft-crystal polymerization of lanthanide complexes
P. P. Ferreira da Rosa, Y. Kitagawa, S. Shoji, H. Oyama, K. Imaeda, N. Nakayama, K. Fushimi, H. Uesaka, K. Ueno, H. Goto, Y. Hasegawa*
Nat. Commun., 13, Article number: 3660 (2022).
DOI: 10.1038/s41467-022-31164-z
- Asymmetric lumino-transformer: Circularly polarized luminescence of chiral Eu(III) coordination polymer with phase-transition behavior
M. Tsurui, Y. Kitagawa, S. Shoji, H. Ohmagari, M. Hasegawa, M. Gon, K. Tanaka, M. Kobayashi, T. Taketsugu, K. Fushimi, Y. Hasegawa*
J. Phys. Chem. B, 126, 3799–3807 (2022).
DOI: 10.1021/acs.jpcb.2c01639
- Application of a new film for horticultural use to convert UV-light to photosynthetic active radiation
S. Kitaoka, T. Shinano, T. Suzuki, S. Shoji, Y. Hasegawa
Eurasian J. For. Res., 22, 73–77 (2022).
DOI: 10.14943/EJFR.22.73
- Tribo-excited chemical reaction using an EuIII complex with a stacked anthracene framework
Y. Kitagawa*, A. Naito, K. Aikawa, K. Shima, S. Shoji, K. Fushimi, Y. Hasegawa*
Chem. Eur. J., 28, e202104401 (2022).
DOI: 10.1002/chem.202104401
- Luminescent Eu(III)-based coordination polymers for photonic materials
Y. Hasegawa*, S. Shoji, Y. Kitagawa
Chem. Lett., 51, 185–196 (2022).
DOI: 10.1246/cl.210650
- Amide-bridged Eu(III) coordination polymer for stable luminescent glass material
J. Hayashi, S. Shoji, K. Fushimi, Y. Kitagawa, Y. Hasegawa*
Mater. Lett., 297, 130012 (2021).
DOI: 10.1016/j.matlet.2021.130012
- In-situ observation of corrosion initiation occurring on NaCl nanoparticles-deposited carbon steel surfaces
K. Fushimi*, H. Okuyama, K. Ohshimizu, S. Shoji, Y. Kitagawa, Y. Hasegawa
Tetsu-to-Hagane, 107(12), 1011–1019 (2021).
DOI: 10.2355/tetsutohagane.TETSU-2021-049
- Zinc 7,8-dihydroxylated chlorophyll-a derivatives as a synthetic model of natural bacteriochlorophyll-a
D. Funakoshi, Y. Nomura, S. Shoji, H. Tamiaki*
Chem. Lett., 49, 1403–1405 (2020).
DOI: 10.1246/cl.200585
- An Europium (III) luminophore with pressure-sensing units: Effective back energy transfer in coordination polymers with hexadentate porous stable networks
Y. Hasegawa*, T. Sawanobori, Y. Kitagawa, S. Shoji, K. Fushimi, Y. Nakasaka, T. Masuda, I. Hisaki
ChemPlusChem, 85, 1989–1993 (2020).
DOI: 10.1002/cplu.202000513
- Covalent heterodyads of synthetic chlorophyll derivatives linked with linear rigid substituents at the 20-positions constructing photoexcited energy transfer systems
S. Shoji*, Y. Nomura, H. Tamiaki*
Tetrahedron, 76, 131130 (2020).
DOI: 10.1016/j.tet.2020.131130
- Synthetic substituted boronates of dihydroxy-bacteriochlorin absorbing and emitting far-red to near-infrared light as bacteriopheophytin-a analogs
D. Funakoshi, Y. Nomura, S. Shoji, H. Tamiaki*
Dyes Pigm., 175, 108155 (2020).
DOI: 10.1016/j.dyepig.2019.108155
- Bioinspired supramolecular nanosheets of zinc chlorophyll assemblies
S. Shoji*, T. Ogawa, S. Matsubara, H. Tamiaki*
Sci. Rep., 9, Article number: 14006 (2019).
DOI: 10.1038/s41598-019-50026-1
日刊工業新聞「葉緑素 微小シート 光合成の仕組みなど解明へ」(2019年10月28日).
朝日新聞デジタル「『人工光合成』実現へ葉緑素を利用」 (2019年10月31日).
Chem-Station 第235回スポットライトリサーチ「葉緑素だけが集積したナノシート」(2019年12月9日).
複合系光機能研究会 ニュースレター No.10 今回の複合光ギャラリー (2020年1月20日).
- Heterodimers of zinc and free-base chlorophyll derivatives co-assembled in biomimetic chlorosomal J-aggregates
S. Shoji*, Y. Nomura, H. Tamiaki*
Photochem. Photobiol. Sci., 18, 555–562 (2019).
DOI: 10.1016/j.dyepig.2018.08.026
- Supramolecular light-harvesting antenna system by co-aggregates of zinc (bacterio)chlorophyll-a derivatives with biomimetic chlorosomal self-assemblies
S. Shoji*, H. Tamiaki*
Dyes Pigm., 160, 514–518 (2019).
DOI: 10.1016/j.dyepig.2018.08.026
- Self-assemblies of zinc bacteriochlorophyll-d analogues having amide, ester, and urea groups as substituents at 17-position and observation of lamellar supramolecular nanostructures
S. Shoji*, T. Ogawa, T. Hashishin, H. Tamiaki*
ChemPhysChem, 19, 913–920 (2018). [Inside Cover]
DOI: 10.1002/cphc.201701044
- Self-aggregation of synthetic chlorophyll-c derivative and effect of C17-acrylate residue on bridging green gap in chlorosomal model
S. Matsubara, S. Shoji, H. Tamiaki*
J. Photochem. Photobiol. A: Chem., 340, 53–61 (2017).
DOI: 10.1016/j.jphotochem.2017.02.021
- Nanotubes of biomimetic supramolecules constructed by synthetic metal chlorophyll derivatives
S. Shoji*, T. Ogawa, T. Hashishin, S. Ogasawara, H. Watanabe, H. Usami, H. Tamiaki*
Nano Lett., 16, 3650–3654 (2016).
DOI: 10.1021/acs.nanolett.6b00781
- In vitro self-assemblies of bacteriochlorophylls-c from Chlorobaculum tepidum and their supramolecular nanostructures
S. Shoji, T. Mizoguchi, H. Tamiaki*
J. Photochem. Photobiol. A: Chem., 331, 190–196 (2016).
DOI: 10.1016/j.jphotochem.2015.11.003
- Synthesis of zinc chlorophyll homo/hetero-dyads and their folded conformers with porphyrin, chlorin and bacteriochlorin π-systems
H. Tamiaki*, K. Fukai, H. Shimazu, S. Shoji
Photochem. Photobiol., 90, 121–128 (2014).
DOI: 10.1111/php.12173
- Pheophytinization kinetics of chlorophyll c under weakly acidic conditions: Effects of acrylic acid residue at the 17-position
K. Sadaoka, S. Shoji, Y. Tsukatani, T. Yoshitomi, H. Tamiaki, S. Kashimura, Y. Saga*
Bioorg. Med. Chem., 21, 6915–6919 (2013).
DOI: 10.1016/j.bmc.2013.09.032
- Reconstruction of rod self-aggregates of natural bacteriochlorophylls-c from Chloroflexus aurantiacus
S. Shoji, T. Mizoguchi, H. Tamiaki*
Chem. Phys. Lett., 578, 102–105 (2013).
DOI: 10.1016/j.cplett.2013.06.012
- Microflow-driven temporal self-assembly of amphiphilic molecules
M. Numata*, M. Takayama, S. Shoji, H. Tamiaki
Chem. Lett., 41, 1689–1691 (2012).
DOI: 10.1246/cl.2012.1689
- Ubiquity and quantitative significance of detoxification catabolism of chlorophyll associated with protistan herbivory
Y. Kashiyama*, A. Yokoyama, Y. Kinoshita, S. Shoji, H. Miyashita, T. Shiratori, H. Suga, K. Ishikawa, A. Ishikawa, I. Inouye, K. Ishida, D. Fujinuma, K. Aoki, M. Kobayashi, S. Nomoto, T. Mizoguchi, H. Tamiaki*
Proc. Natl. Acad. Sci., USA, 109, 17328–17335 (2012).
DOI: 10.1073/pnas.1207347109
- Construction of chlorosomal rod self-aggregates in the solid state on any substrates from synthetic chlorophyll derivatives possessing an oligomethylene chain at the 17-propionate residue
S. Shoji, T. Hashishin, H. Tamiaki*
Chem. Eur. J., 18, 13331–13341 (2012). [Back Cover]
DOI: 10.1002/chem.201201935
- Self-assembly of zinc bacteriochlorophyll d derivative possessing a triethoxysilyl group at the 17-propionate residue
N. Takahashi, S. Shoji, H. Tamiaki, Y. Saga*
Bull. Chem. Soc. Jpn., 85, 989–994 (2012).
DOI: 10.1246/bcsj.20120043
- Photooxidative cleavage of zinc 20-substituted chlorophyll derivatives: conformationally P-helix–favored formation of regioselectively 19–20 opened linear tetrapyrroles
H. Tamiaki*, Y. Okamoto, Y. Mikata, S. Shoji
Photochem. Photobiol. Sci., 11, 898–907 (2012).
DOI: 10.1039/C1PP05301A
著書 / Books
- Lanthanide-Based Wavelength Conversion Materials
Y. Hasegawa*, Y. Kitagawa, S. Shoji
Springer Singapore (2024).
- 希土類錯体蛍光体の植物育成への応用
庄司 淳, 長谷川靖哉, 北川裕一, 鈴木 卓, 斎藤秀之
〈続〉次世代蛍光体材料の開発, シーエムシー出版, 111–118 (2024).
- MgN4
民秋 均, 庄司 淳
錯体化合物事典, 錯体化学会編, 朝倉書店, 450 (2019).
- ZnN4
民秋 均, 庄司 淳
錯体化合物事典, 錯体化学会編, 朝倉書店, 875 (2019).
その他 / Others
- ユウロピウム錯体塗布農業用フィルムの被覆による植物の成長促進
鈴木 卓, 斎藤秀之, 庄司 淳, 長谷川靖哉
バイオサイエンスとインダストリー(B&I), 81(5), 412–413 (2023).
- 紫外線を赤色光に変換するフィルムによる植物の成長促進効果
鈴木 卓, 斎藤秀之, 庄司 淳, 長谷川靖哉
バイオサイエンスとインダストリー(B&I) 目で見るバイオ, 81(5), 390–391 (2023).
- 光合成アンテナ研究から農業へ
庄司 淳
カーボン・エネルギー社会協議会(CanApple)ニュースレター, 第191号 (2021).
- 生物から学ぶ効率的な光合成システム –分子レベルで設計された人工光捕集アンテナの構築–
松原翔吾, 庄司 淳, 民秋 均
化学, 76(5), 70–71 (2021).
- 希土類錯体分子の構造異性体を利用した光線力学診断と療法の両立
庄司 淳
ぶんせき, 日本分析化学会編, 9, 341 (2020).
- 緑色光合成細菌の光捕集アンテナを模倣したクロロフィル自己集積体のナノ構造観察
庄司 淳, 小川哲也, 民秋 均
NanotechJapan Bulletin, 13(1), 1–6 (2020).
- 天然/人工光合成アンテナの構造・機能と開発動向
庄司 淳, 民秋 均
MATERIAL STAGE, 技術情報協会, 16(11), 36–42 (2017).